Yea mate I think it was my ph being well off I think I was messing with ph down too much as it has settled when I left it alone doesn't help my ph pen was about 1.0 out of calibration. Canna aqua says on the grow schedule to maintain from 5.2 to 6.2 but it also mentions it has ph stabilisation in the nutrients I am thinking it is trying to reach 5.8 and it did last night and was OK this evening so gonna try and maintain this and see what happens.
My experience with canna and pH is that after I mix canna I let it sit for an hour before doing anything regarding plants. Its pretty stable but I've found big swings in it before I let it set. Much easier to adjust it that way.