You could probably start using the nutrients this week considering you are already seeing your first set of true leaves. Generally you would want to begin feeding at your first set at about 1/4 recommended dosage. I will add a caveat. If you don't feel comfortable feeding them this early then wait. That is fine too. You aren't going to kill them by slightly underfeeding them.
On the question about the trio, that is an excellent question by the way and one most new growers don't make until half way through their grow. Because we don't have a traditional Veg and Bloom cycle like photoperdiods, the typical scenario everyone that grows autos with is: You use your Veg bottles as prescribed on the manufacturer's feeding schedule until you see vertical growth stop. Once vertical growth stops you will switch to your Bloom bottles.
I will give you some reasoning, instead of just telling you what you should do. Hopefully that enables you to make a more informed decision of when is best for you to determine to change formulas. Because while most everyone sticks to this rule, there are always exceptions and personal preference. The reason behind this is, you want to get as much vertical growth out of the plants as possible before starting with Bloom nutrients. If you switch too early then you are effectively removing the majority of your Nitrogen from the regimen and will not only retard any vertical growth that may be left in them but also root growth. So long as your plant is growing up, your roots are growing down and out. The larger the root ball you can develop, the more flowers the plant will produce. So, while autos are somewhat conditioned to flower without a light change you do have some control over their flowering by nutrient regimen. They will still begin to flower but they won't put all of their energy into flowering so long as you are feeding high levels of N. They will continue to try and grow vertically. Just as photoperiods, even when we switch the light to 12/12 we still feed N for the following two weeks because of that stretch early in flowering.