Ok i have been told another theory as to why we are seeing Cal/mag def under Led... The theory goes like this, because LED's don't give out the same radiant heat as HPS the plants don't transpire as they normally would, this in turn changes how the plant uptakes nutrients. i have been adviced that a way around this, is to increase the temps and the RH in the grow room. this is what i am doing at the moment..running temps between 82-86F and an RH of 70-80%, so far no problems. Will keep you all updated on how this theory works out.