Plant looks very healthy! Which GH nutrients are you using, and how much per gallon? How about humidity in the tent?
Over feeding is possible, as is root rot. That said, I almost always get a bit of PH drop late in bloom in hydro, just not down to 4, and not this early. That's a bit concerning.
I've tried Hygrozyme (now called Igrowslime, as that's all it did for me.) Peroxide works ok, but all I use now is a couple drops of bleach per gallon, or 1ml per 10 gal.
You will hear people scream, moan, and throw fits over it sometimes, but it works great, and is dirt cheap. It's actually a micro nutrient.
Currently running at 2 drops per gallon:
From my old co2 sealed cab in 2013. 1 ml per 10 gal in RDWC. Bone white roots under there!
The more details you can throw at us, the better we can help.
Regards, Kyle