True Colloidal Silver Nanoparticles Easily and Safely Made at Home

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I'm kind of new here, but I figured I'd share this commonly used method of making "True Colloidal Silver Nanoparticles" easily, and relatively safely at home. This is Woo-Free.

You're not going to have to buy any (pure) silver wire, a piece of bullion that you might have to give your ID to buy, no electrical transformers using deadly, or at least harmful (.1 to .2 amps WILL kill you, while more will usually only burn you and/or knock you the f**k right out, requiring artificial respiration to avoid death) amperage or voltages.
Straight up, you're going to need silver nitrate (yeah, that stuff again), distilled water, plain old food grade (or better) citric acid (trisodium citrate)... and a transparent (so you can see a faint color change), heat resistant beaker or vessel.

I want to stress that this is true colloidal silver, as compared to ionic silver. This has a zero charge on the silver atom, and is truly made of real nanoparticles that you won't see, unlike the ionic method using STS, or the "flaky" silver electrolytic method. Electrolytically-derived silver is actually a mixture of ionic and colloidal silver. When people talk about the effectiveness of "colloidal silver", and they're using electricity to make it, are they half telling the truth, or are they half lying? I don't know, I always use the STS method myself, but so many people swear up and down on colloidal silver that I just wanted to introduce this easy method of producing true silver nanoparticles of colloidal silver used in materials labs worldwide. Being true nanoparticles, take care and use the usual safety precautions associated with nanotechnology.

The basic idea, the reaction behind it, is as follows:
4Ag(+) + C6H5O7Na3 + 2H2O → 4Ag(0) + C6H5O7H3 + 3Na(+) + H(+)+ O2↑
The sign in parentheses indicates the charge, or lack of, on the ion or atom.
The nitrate is in the water, and not necessary in the reaction, it does match up (the 3Na(+) and the H(+))with the equation, though. Don't worry about the possible variance in the sodium ions in the equation due to using the various (mono, di, or trisodium) salts of citric acid.

That all taken care of, here is the generally safe and easy procedure. Avoid breathing in any dust from the silver nitrate, wear gloves while handling it, and don't burn yourself on the boiling water. Why not go all "chem lab", and wear some (safety) glasses, too.

1.a) Make a solution of 0.25 grams of the silver nitrate and enough distilled water to make a 500mL volume of solution. (This is a .003M solution, given that the mole weight of silver is ~108.87g.)
b) Make a separate solution of .25 grams of citric acid in enough distilled water to make a 250mL volume of solution. (a simple 1% solution, basically)

2.) Bring the silver nitrate solution to boiling.

3.) Add, drop by drop, 50mL of the citrate solution to the boiling solution while stirring or mixing the boiling solution.

4.) continue heating the solution until it appears a faint or pale yellow color.

5.) Let it cool until appropriate for use (spraying).

Yup, that is WAY easy.
The hardest part will probably be getting the silver nitrate, which you can usually find on ebuy, or wherever. It's not controlled, watched, or even suspected. There are MANY uses for it, even at home, that you could give any (nosy) person that might want to know what you want it for. You can get citric acid in most grocery stores, let alone most likely where you found the Silver nitrate. If you really want to get specific, get "trisodium citrate", food grade, analytical grade, or tech grade, whatever...

Now, at a roughly (yes, it is in fact a bit less, but...) .003M solution (approximately 3000 micromoles/L), this amount of silver is considerably (exponentially) larger than the STS concentrations of something under 150 micrograms per plant needed to effect sex reversal (as reported in the literature), you could dilute it (with distilled water, of course) to one-tenth or one-twentieth strength (or to whatever, even smaller if you might use mulitiple applications - if you're smart enough to play with chemicals, you can do all the math yourself, as you're reading this on a computer with a calculator, or can find an online one... I ain't going there), or just make a much smaller amount, according to your needs, assuming that colloidal silver is as effective as ionic silver...

...Which I really don't care about, as I have a near-lifetime supply of STS at my disposal.

Hopefully, if your inspired to try to use this method in sex reversal/feminization, and colloidal silver does in fact work as good as so many say it does, then post some results here, I'm interested to see... even though I'm sticking with the STS method myself.
 
I'm kind of new here, but I figured I'd share this commonly used method of making "True Colloidal Silver Nanoparticles" easily, and relatively safely at home. This is Woo-Free.

You're not going to have to buy any (pure) silver wire, a piece of bullion that you might have to give your ID to buy, no electrical transformers using deadly, or at least harmful (.1 to .2 amps WILL kill you, while more will usually only burn you and/or knock you the f**k right out, requiring artificial respiration to avoid death) amperage or voltages.
Straight up, you're going to need silver nitrate (yeah, that stuff again), distilled water, plain old food grade (or better) citric acid (trisodium citrate)... and a transparent (so you can see a faint color change), heat resistant beaker or vessel.

I want to stress that this is true colloidal silver, as compared to ionic silver. This has a zero charge on the silver atom, and is truly made of real nanoparticles that you won't see, unlike the ionic method using STS, or the "flaky" silver electrolytic method. Electrolytically-derived silver is actually a mixture of ionic and colloidal silver. When people talk about the effectiveness of "colloidal silver", and they're using electricity to make it, are they half telling the truth, or are they half lying? I don't know, I always use the STS method myself, but so many people swear up and down on colloidal silver that I just wanted to introduce this easy method of producing true silver nanoparticles of colloidal silver used in materials labs worldwide. Being true nanoparticles, take care and use the usual safety precautions associated with nanotechnology.

The basic idea, the reaction behind it, is as follows:
4Ag(+) + C6H5O7Na3 + 2H2O �� 4Ag(0) + C6H5O7H3 + 3Na(+) + H(+)+ O2��
The sign in parentheses indicates the charge, or lack of, on the ion or atom.
The nitrate is in the water, and not necessary in the reaction, it does match up (the 3Na(+) and the H(+))with the equation, though. Don't worry about the possible variance in the sodium ions in the equation due to using the various (mono, di, or trisodium) salts of citric acid.

That all taken care of, here is the generally safe and easy procedure. Avoid breathing in any dust from the silver nitrate, wear gloves while handling it, and don't burn yourself on the boiling water. Why not go all "chem lab", and wear some (safety) glasses, too.

1.a) Make a solution of 0.25 grams of the silver nitrate and enough distilled water to make a 500mL volume of solution. (This is a .003M solution, given that the mole weight of silver is ~108.87g.)
b) Make a separate solution of .25 grams of citric acid in enough distilled water to make a 250mL volume of solution. (a simple 1% solution, basically)

2.) Bring the silver nitrate solution to boiling.

3.) Add, drop by drop, 50mL of the citrate solution to the boiling solution while stirring or mixing the boiling solution.

4.) continue heating the solution until it appears a faint or pale yellow color.

5.) Let it cool until appropriate for use (spraying).

Yup, that is WAY easy.
The hardest part will probably be getting the silver nitrate, which you can usually find on ebuy, or wherever. It's not controlled, watched, or even suspected. There are MANY uses for it, even at home, that you could give any (nosy) person that might want to know what you want it for. You can get citric acid in most grocery stores, let alone most likely where you found the Silver nitrate. If you really want to get specific, get "trisodium citrate", food grade, analytical grade, or tech grade, whatever...

Now, at a roughly (yes, it is in fact a bit less, but...) .003M solution (approximately 3000 micromoles/L), this amount of silver is considerably (exponentially) larger than the STS concentrations of something under 150 micrograms per plant needed to effect sex reversal (as reported in the literature), you could dilute it (with distilled water, of course) to one-tenth or one-twentieth strength (or to whatever, even smaller if you might use mulitiple applications - if you're smart enough to play with chemicals, you can do all the math yourself, as you're reading this on a computer with a calculator, or can find an online one... I ain't going there), or just make a much smaller amount, according to your needs, assuming that colloidal silver is as effective as ionic silver...

...Which I really don't care about, as I have a near-lifetime supply of STS at my disposal.

Hopefully, if your inspired to try to use this method in sex reversal/feminization, and colloidal silver does in fact work as good as so many say it does, then post some results here, I'm interested to see... even though I'm sticking with the STS method myself.

and could you drink this "silver nitrate" solution ?

if useing electricity is not colloidal silver but in fact ionic silver , why were people calling it coloidal silver 40 years ago ? and why are chemists YES official ones calling it so today ? ive only recently started seeing mention of this so i chalked it up to nay sayers trying to cause doubt

anyway , back to my main question , would you drink this "silver nitrate" solution ? if not why ? go into detail please and do not simply say you dont want to turn blue because that is a load of crap

thanx for the post
 
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doing just a little quick searching verifies at least to me that my thought on the matter is correct and useing electricity does in FACT make colloidal silver

here is a little copy n paste from many things ive found rather quickly/easilly ,,,,,,

The World Health Organization includes silver in a colloidal state produced by electrolysis of silver electrodes in water, and colloidal silver in water filters as two of a number of water disinfection methods specified to provide safe drinking water in developing countries.[47]

could it be that the " World Health Organization " is wrong ?

please post some evidence or i will strongly edit your post to a simple making of silver feminized spray

thanx in advance
 
Sorry to get off topic bob, but I crack up every time I read your signature:crying:
 
and could you drink this "silver nitrate" solution ?

If diluted to the concentrations cited in the literature for sex reversal in cannabis, I wouldn't have much of a problem with trying some... I'd be much more worried about the nitrate in the solution as opposed to the neutrally-charged silver, although I wouldn't recommend ingesting ANY nanoparticulate matter. Of course, it wouldn't be much different than eating a small pellet of silver along with a sausage made with some citric acid and sodium nitrate.

The World Health Organization includes silver in a colloidal state produced by electrolysis of silver electrodes in water, and colloidal silver in water filters as two of a number of water disinfection methods specified to provide safe drinking water in developing countries.[47]

could it be that the " World Health Organization " is wrong ?

please post some evidence or i will strongly edit your post to a simple making of silver feminized spray

thanx in advance

First, I never said that electrolytically isolated silver (EIS) wasn't colloidal silver... I wrote "Electrolytically-derived silver is actually a mixture of ionic and colloidal silver." I have no doubt that there is some colloidal silver in these preparations.

Second, I checked the wikipedia-referenced UN document you indicated in your post.... the following is from pages 148-9 of the document:

"Three methods are used for disinfection with silver. The first or “contact”
method requires the passage of the water through silver saturated devices, such as
tanks with walls and screens coated with special silver-containing paint. The second
method consists of dosing low concentration silver solutions in the same way used
for chlorine solutions, with similar equipment and feeders. The third, electrolytic,
method appears to be the most practical. A number of silver electrodes are
connected to the positive pole (anode) of a low power electric source. An inert
electrode is used as a negative pole, where hydrogen is produced and freed. Through
electrolysis, the silver ions are freed by the electrodes inside the water current to
be treated in proportion to the supply current. The method is appropriate, for the
dose can be varied by changing the current."

I'm reading something about what the silver electrodes do in the second to last sentence of that paragraph... "Through
electrolysis, the silver ions are freed by the electrodes inside the water current to
be treated in proportion to the supply current."
"Silver ions."
No, I certainly do not claim that the WHO could be wrong.

As far as "proof" goes, I cannot prove a negative... I can, however prove a positive, and that positive would be that the preparation I have in fact described is in fact made of "True Colloidal Silver Nanoparticles."

Here is the source which I offer as "proof".

Analysis of Silver Nanoparticles Produced by Chemical Reduction of Silver Salt Solution
Asta ŠILEIKAITĖ, Igoris PROSYČEVAS, Judita PUIŠO,Algimantas JURAITIS, Asta GUOBIENĖ
ISSN 1392–1320 MATERIALS SCIENCE (MEDŽIAGOTYRA). Vol. 12, No. 4. 2006

You can check out the whole article here: http://internet.ktu.lt/lt/mokslas/zurnalai/medz/pdf/medz0-87/03 Electronic...(pp.287-291).pdf
In conclusion, the citrate acts as a reduction agent, creating a colloidal silver solution, rather than "a simple making of silver feminized spray".

I'm sure that's what you were looking for.

I didn't come here to pick a fight, I came to share some real, helpful, as well as easily and safely applied knowledge. As you are a moderator, I really do appreciate that you want to make sure everything is "on the up and up".
 
I'm a user of b0bs CS method myself and always have fantastic results. I do make the CS with my own battery powered generator but the principle is the same. I'm also about to do a comparison between CS and STS but now I might have to try this method also and compare all 3.....I like science :thumbs:
 
without looking much into this the one thing that stands out to me that im not fond of is "Analysis of Silver Nanoparticles Produced by Chemical Reduction of Silver Salt Solution" salt being the key word

would like to mention that making c.s with low voltage is very safe , ive crossed my wires while in the water many times without blowing up or ending up with an unwanted perm (not that i have enough hair anyway)

but yes mjc you are correct , i do want the comunity to have the best info possible , not to down play your info (i did thank you for the post in my original reply) but imo the colloidal tutorial ive posted is about the best a person could use if they want c.s for BOTH reversing plants and health bennefits for humans

peace :Cool:
 
Hello! About to try this method. Stupid question but this is safe for human consumption, correct? Or at least as safe as an ionic solution right?
 
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