Hey aaran,
Your pH is above recommended line of around 6.3/6.5. Feeding at lowered numbers might help improve your soil conditions, but it's a slower fix. Flushing with half amount of water at 6.3 will improve your soil's condition and start the healing process.
It looks a lot like Early Leaf Spots funghus. Are those spots a lighter shade of brown on the underneath of leafs? If so, it will not be easy to erradicate, I tell you. There's no quick fix for this.
There are several types of leaf spot funghi, and each manifest differently on the shape and color of spots. The spores travel by air and usually infest the air system environment. It's relatively common that the funghi spores survive within seasons.
You'll need to improve your air flow, removing the infected leafs is advised as it will improve the air flow and remove troubled leafs. They need to be discarded. There are a few solutions you should try to see which fits you best: neem oil is more preventive, garlic solutions are both preventive and health enhancer, baking soda is known to have been used but it does add sodium to your environment, Seaweed hardens the leaf surfaces, Citrofresh as shown some results on erradication and also Copper oxides.
I recommend you take a good long read at this thread over here:
http://www.uk420.com/boards/index.php?showtopic=72916
There are several other resources online as this is somehow a common problem in many crops:
http://jnkvv.nic.in/IPM Project/disease-groundnut.html#Late_leaf_spot_
IMO it's not a nute problem. It's also unluckily pH to be the only culprit. If any other grower would chip in it would be great
Ps - thanks for the trust Kush