I think you may have got your calculations wrong..not 100% sure but, when looking at the bottle I have it's showing as calcium 4%, magnesium 1% , so 2% Nitrogen would be half the amount of calcium and double the magnesium, unless I've misunderstood.
Either way, to say "if you're using more than 100ppms of cal/mag you're using too much" is very much a sweeping statement, because a grower could be using RO water, and could need more than that to get in the 'ideal range' in my opinion.
Most nutrient lines are giving more than enough Nitrogen, so a small increase of Nitrogen in the calmag each fertigation can lead to clawing and obvious signs of N toxicity..this can lead to other issues as we know.