pardon the delay mate!
... yup, as suspected, way off pH
,.... 5.6 is an estimation, but a reasonably accurate one I believe... As for the 7.0 water, that depends on how hard the water is, it's CaCO3 content, measured by TDS meter (ppm's) or an EC meter,... did you pH adjust this water, or is it "as is" from the tap? If so, then at 7.0, it's pretty soft water, which is good indeed! If it's hard water that you adjusted, then this is where the measurement skewing will be, likely making the reading less acidic that it really is,.. but the slurry test is better than run-off test and calculation!
I admit, I'm a little shocked the other plants are doing okay,... how old are they? I won't tell you to fix what ain't showing as broke, but yes, I'd stay with watering at 7.0, maybe higher... back to that water hardness deal again-- more minerals in there will offer stronger pH buffering. do you have a Ca-mg product? .... I strongly recommend a basic, inexpensive TDS meter so you can test your water and just see,...ditto for a pH probe, like the Accurate 8-
hsoil:- (the long probe unit here)... avoid the cheapo skinny probes you see around at garden centers, etc., they suck! Big picture here is, having such tool will help you understand and adjust your water and nutes better, and more important,keep an eye on the in-pot pH,.. adjusting your water/nutes (if needed) will go a long way to maintaining proper pH in-pot! It's 10x the beating to fix off-pH in pot vs. making little tweaks here and there to help maintain it; there are several other influencing factors in-pot as well, from the roots themselves to the soil microbes,... do you use any inoculants, BTW?
.. watering,... I think when the pot is 50% lighter than when well watered, it's time,.. but weighing is a pain, so that's why I say to learn the heft test; just "calibrate" yourself with wet and dry-ish (not totally!) ones,... seedlings want more even consistent moisture levels,.. some surface drying is oK, but never to the point of then stressing/wilting....
... a wet hand towel hung in a open well spread way (more surface area exposed) can help in a tent, maybe squeak out another 5-10%RH,....
....looking at that LSD, it's very yellow on newest growth (not sure how much the light is behind this?),.. but such symptoms indicate a defc. in an immobile nute element, usually Fe or Zn,... odd at such a young age,... oder still, it's usually happens when the soil gets near 7.0 pH, which ain't the cae here, so it's likely a uptake quirk causing a lack-of type defc., not a pH lockout type,... I've had some plants like this, fought the defc. for weeks before finally getting ahead of it,... goes back to that sub-par seedling thing, a gamble with all seeds,....
shweeet!- on the HPS! Make sure it's plenty high up, seedling don't like the intensity of light that older plants do,.. and down-side, your struggles with RH% just got worse, unless yours is ducted and cooled very well,...