Calcium deficiency? Phosphorus? Only one plant of 3 in dwc.

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There are 3 plants in this dwc tote. 2 bubblelicious and one blue cheese, 9 weeks and well into flower. Brown spots affecting only one bubblelicious. Water temps average 68° (I have a chiller I alternate between 2 totes). Room temp not above 80° or below 70° depending on lights on/off. Mixing GH nutes throughout this grow 1 part micro 2 parts bloom, and 1 part calmag. Ppm is at its max or they start developing leaf curl. pH has always been 5.8-6.1. rh 45 - 55%
I just did a rez change last week
Any ideas what this is and why only one plant? IMG_20191212_054438649.jpg
 

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Looks like there starting to wind down and should be ready to chop soon.
 
Looks like there starting to wind down and should be ready to chop soon.
This particular plant IS further along than the others so if it is an ailment I hope she can make it before it gets too much worse. I can never tell by looking several times a day if more leaves are spotting or it has stopped.
 
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