Help please with this

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41 day old GG4 . Been real healthy for whole grow and the all of a sudden showed this on upper leaves just in last day.
Having a hard time nailing what it could be. 4 other plants on tent don’t show same

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Fill out the infirmary section. These guys know there shit
 
Problem: see pics above yellow and browning spots on upper leaves

Medium/grow method: 50% happy frog 40% ocean forest 10% light warrior

Feed: and supplements used: really only 1 tablespoon of big bloom per gallon last couple weeks. Before that nada. Soil had the nutes Last feeding added less than 1/2 teaspoon of tiger bloom/ gallon

water source: tap water ppm around 200 reads about 9 ph. Bring it down with gh ph down to 6.3-6.5

Strain/age: gorilla glue 4, 41 days

light used: 400 watt HPS. about 16 inches from tops

Climate: 80 degrees F 45% RH

Additional info: other strains in tent ( 5 plants total including another gg4 not showing same symptom
 
Just one leaf? Did you tuck that leaf under another? Or was it possible under another plants leaf?
 
Ok. Well hopefully one of the many experts here will help you figure it out. Good luck. Happy growing
 
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