Grow Mediums Chiller spiking pH

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So Im starting a new grow and taking a break from coco. I decided to do another RDWC run because Ive liked doing them in the past but its been some years since my last time. I bought some bulkheads and pots from PA hydroponics and pieced together the rest. The total water capacity is about 50 gallons including the reservoir. Im getting ready to drop 4 different strains... Anvil, Black Strap(breeders reserve), Kaleidoscope 2 and Strawberry Cheese.

Ive spent the last week dialing the environment and water in before I start the seeds and stumbled across a weird issue today. I monitor the pH and such with the guardian and have secondary pens for redundancy. I hooked up an old chiller I had sitting in the garage yesterday and noticed the pH climbed a full point over night. It hadn't done that all week. While it did climb, it did so very gradually which from what I remember is mostly normal. Without boring you with the details, Ive narrowed it down to the chiller. When water circulates through it, the climb in pH is much more rapid then when the pump feeding it is off.

The chiller is a JBJ Arctica which I used to use in a saltwater aquarium like 10 years ago but as I said, its been sitting in the garage collecting dust. I pulled it inside 3 days ago, cleaned it off and ran a mixture or H2O2 through it for a few hours and then spent the next day flushing it with regular water. I figured this would kill and/or clean out the insides so it would be good to go. When its disconnected from my setup, the pH is relatively stable. When water cycle through it and my sump the pH climbs quickly.

Has anyone ever encountered something like this? Could it be a bacteria issue? The only other thing I can think to do is to cycle a solution of bleach through it and flush again and try again... thoughts?
 

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Are you sure it's the chiller? Can you run chiller in an isolated environment? Perhaps have it cycle water through a bucket for an extended period? My thinking is to remove the variables. At the moment, you're got the chiller cycling water into a complex environment. If you isolate the chiller, you're removing all variables.

If it truly is the chiller and there's bacteria in it, what is the bacteria feeding on? It would need some source of nutrient, right? Another thought - could there be a chemical reaction somewhere in the environment that's increasing pH due to leaching of some kind. I read a report about a year ago where a grower changed a plastic fitting for a copper fitting. It took some time for the issue to manifest but it whomped him when it did. It took him many hours to figure out that the copper was the culprit.

Re. you setup - very impressive. "dress right, dress" comes to mind.

Re. bleach - I'd do that after isolating the chiller so that you're not changing two things at once. I didn't catch this about bleach when I cleaned my res last summer. Don't get the "no spill" flavor. It's highly diluted. Go with the high octane stuff and it will destroy bacteria on contact.
 
So I figured I’d update. After running that chiller for a while, I was having to add so much pH down that it started raising ppms. I was adding it constantly! I ended up buying a new chiller. I’m happy to report that with the new chiller hooked up, pH has been rock solid. There must’ve been something inside the old one that was causing an issue.
 
So I figured I’d update. After running that chiller for a while, I was having to add so much pH down that it started raising ppms. I was adding it constantly! I ended up buying a new chiller. I’m happy to report that with the new chiller hooked up, pH has been rock solid. There must’ve been something inside the old one that was causing an issue.
Good to see that you got the issue resolved. Sometimes you get to the point where makes more sense to write the check.
 
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